Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale     

Dale P. Cruikshank  Allan W. Meyer  Roger N. Clark  Katrin Stephan  Scott A. Sandford  Gianrico Filacchione  Philip D. Nicholson  Thomas B. McCord  J. Brad Dalton  Dennis L. Matson 《Icarus》2010,206(2):561-572

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.  相似文献   

International collaboration on marine bioinvasions--the ICES response     

Gollasch S 《Marine pollution bulletin》2007,55(7-9):353-359

The International Council for the Exploration of the Sea (ICES) noted the risks associated with uncontrolled species introductions and transfers more than 40 years ago and launched two working groups to address the issue, i.e. the ICES Working Group on Introductions and Transfers of Marine Organisms (WGITMO) to deal with the movement of non-indigenous species for e.g. aquaculture purposes and the ICES/IOC/IMO Working Group on Ballast and Other Ship Vectors which focuses on species movements with ships. Both groups are actively working until today and the key achievements of the groups are outlined.  相似文献   

Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site     

Thomas Pape  André Bahr  Janet Rethemeyer  John D. Kessler  Heiko Sahling  Kai-Uwe Hinrichs  Stephan A. Klapp  William S. Reeburgh  Gerhard Bohrmann 《Chemical Geology》2010,269(3-4):350-363

Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C₁–C₄, CO₂]). Molecular ratios of LMWHC (C₁/[C₂ + C₃] > 1000) and stable isotopic compositions of methane (δ¹³C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C₁/C₂₊ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C₁–C₄, CO₂]) relative to the other gas types and the virtual lack of ¹⁴C–CH₄ indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C₁–C₄, CO₂)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of ¹⁴C–CH₄ (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.  相似文献   

Scientific uncertainty and climate change: Part II. Uncertainty and mitigation     

Stephan Lewandowsky  James S. Risbey  Michael Smithson  Ben R. Newell 《Climatic change》2014,124(1-2):39-52

In public debate surrounding climate change, scientific uncertainty is often cited in connection with arguments against mitigative action. This article examines the role of uncertainty about future climate change in determining the likely success or failure of mitigative action. We show by Monte Carlo simulation that greater uncertainty translates into a greater likelihood that mitigation efforts will fail to limit global warming to a target (e.g., 2 °C). The effect of uncertainty can be reduced by limiting greenhouse gas emissions. Taken together with the fact that greater uncertainty also increases the potential damages arising from unabated emissions (Lewandowsky et al. 2014), any appeal to uncertainty implies a stronger, rather than weaker, need to cut greenhouse gas emissions than in the absence of uncertainty.  相似文献   

A study of hybrid and chaotic long-range propagation in a doublesound channel environment     

Noel  C. Viala  C. Stephan  Y. 《Oceanic Engineering, IEEE Journal of》1999,24(4):447-457

This paper presents the results of the analysis of long range propagation (~200 km) in a range-dependent environment. The propagation medium is characterized by two deep sound channels. The range dependence enables energy transfer between the channels and leads to a mismatch between real data and ray predictions. To explain this mismatch, an analysis of hybrid ray propagation is presented. This analysis is completed by an interpretation in terms of chaos. This chaos is quantified in the particular case of the Bay of Biscay environment. This paper puts forward that mesoscale perturbations, such as the Mediterranean outflow in the North Atlantic, can affect long-range propagation. However, it shows that the ray theory remains reliable for a propagation range of several hundred kilometers  相似文献   

Response of precipitation over Greenland and the adjacent ocean to North Pacific warm spells during Dansgaard–Oeschger stadials     

Thorsten Kiefer  Stephan Lorenz  Michael Schulz  Gerrit Lohmann  Michael Sarnthein  Henry Elderfield 《地学学报》2002,14(4):295-300

ABSTRACT Palaeoceanographic reconstructions from the North Atlantic indicate massive ice breakouts from East Greenland near the onset of cold Dansgaard–Oeschger (D–O) stadials. In contrast to these coolings in the North Atlantic area, a new sea-surface temperature record reveals concomitant warm spells in the northern North Pacific. A sensitivity experiment with an atmospheric general circulation model is used to test the potential impact of sea-surface warmings by 3.5 °C in the North Pacific, on top of otherwise cold stadial climate conditions, on the precipitation regime over the Northern Hemisphere ice sheets. The model predicts a maximum response over East Greenland and the Greenland Sea, where a 40% increase in net annual snow accumulation occurs. This remote effect of North Pacific warm spells on the East Greenland snow-accumulation rate may play an important role in generating D–O cycles by rebuilding the ice lost during ice breakouts. In addition, the increased precipitation over the Greenland Sea may help to sustain the D–O stadial climate state.  相似文献   

The geomorphology and sedimentology of the ‘Témpanos’ moraine at Laguna San Rafael,Chile     

Neil F. Glasser  Krister Jansson  Wishart A. Mitchell  Stephan Harrison 《第四纪科学杂志》2006,21(6):629-643

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Modeling of SMF tsunami hazard along the upper US East Coast: detailed impact around Ocean City,MD   总被引：1，自引：0，他引：1  

Stephan T. Grilli  Christopher O’Reilly  Jeffrey C. Harris  Tayebeh Tajalli Bakhsh  Babak Tehranirad  Saeideh Banihashemi  James T. Kirby  Christopher D. P. Baxter  Tamara Eggeling  Gangfeng Ma  Fengyan Shi 《Natural Hazards》2015,76(2):705-746

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Getting Lost in Cities: Spatial Patterns of Phonetically Confusing Street Names          下载免费PDF全文

Keith Chan  Maria Vasardani  Stephan Winter 《Transactions in GIS》2015,19(4):535-562

A large street network is likely to contain duplicated or similar sounding street names. These conflicts can cause confusion in communication between people or in machine‐human interaction. Municipal authorities have begun to see the importance of uncovering these existing street name conflicts and mitigating future ones, for improved record keeping, emergency response, etc. However the commonly used Soundex phonetic algorithm is generally considered to produce poor similarity results in terms of uncovering street name conflicts. This study reports on a new fusion algorithm that combines phonetic methods and approximate string matching for street names, weighted by street type suffix (Avenue, Boulevard, Court, etc.), to quantitatively measure the collision/confusion potential presented by a pair of streets. This algorithm is then applied to the entire street network in Greater Melbourne, Australia, and the pattern of collisions at various spatial scales, and within municipalities, is mapped. The goal of this work is to produce better tools that can aid policy makers, administrators and industries dealing with location‐based services to make better decisions when assigning and disambiguating street names.  相似文献   

Urban green commons: Insights on urban common property systems   总被引：1，自引：0，他引：1  

Johan Colding  Stephan Barthel  Pim Bendt  Robbert Snep  Wim van der Knaap  Henrik Ernstson 《Global Environmental Change》2013,23(5):1039-1051

The aim of this paper is to shed new light on urban common property systems. We deal with urban commons in relation to urban green-space management, referring to them as urban green commons. Applying a property-rights analytic perspective, we synthesize information on urban green commons from three case-study regions in Sweden, Germany, and South Africa, and elaborate on their role for biodiversity conservation in urban settings, with a focus on business sites. Cases cover both formally established types of urban green commons and bottom-up emerged community-managed habitats. As our review demonstrates, the right to actively manage urban green space is a key characteristic of urban green commons whether ownership to land is in the private, public, the club realm domain, or constitutes a hybrid of these. We discuss the important linkages among urban common property systems, social–ecological learning, and management of ecosystem services and biodiversity. Several benefits can be associated with urban green commons, such as a reduction of costs for ecosystem management and as designs for reconnecting city-inhabitants to the biosphere. The emergence of urban green commons appears closely linked to dealing with societal crises and for reorganizing cities; hence, they play a key role in transforming cities toward more socially and ecologically benign environments. While a range of political questions circumscribe the feasibility of urban green commons, we discuss their usefulness in management of different types of urban habitats, their political justification and limitation, their potential for improved biodiversity conservation, and conditions for their emergence. We conclude by postulating some general policy advice.  相似文献